Preferred Label : field effect;
IUPAC definition : An experimentally observable effect symbolized by F (on reaction rates, etc.) of intramolecular
coulombic interaction between the centre of interest and a remote unipole or dipole,
by direct action through space rather than through bonds. The magnitude of the field
effect (or 'direct effect') depends on the unipolar charge/dipole moment, orientation
of dipole, shortest distance between the centre of interest and the remote unipole
or dipole, and on the effective dielectric constant.;
Origin ID : F02358;
Automatic exact mappings (from CISMeF team)
- See also
An experimentally observable effect symbolized by F (on reaction rates, etc.) of intramolecular
coulombic interaction between the centre of interest and a remote unipole or dipole,
by direct action through space rather than through bonds. The magnitude of the field
effect (or 'direct effect') depends on the unipolar charge/dipole moment, orientation
of dipole, shortest distance between the centre of interest and the remote unipole
or dipole, and on the effective dielectric constant.
