Preferred Label : mesomeric effect;
IUPAC definition : The effect (on reaction rates, ionization equilibria, etc.) attributed to a substituent
due to overlap of its p- or π-orbitals with the p- or π-orbitals of the rest of the
molecular entity. delocalization is thereby introduced or extended, and electronic
charge may flow to or from the substituent. The effect is symbolized by M. Strictly
understood, the mesomeric effect operates in the ground electronic state of the molecule.
When the molecule undergoes electronic excitation or its energy is increased on the
way to the transition state of a chemical reaction, the mesomeric effect may be enhanced
by the electromeric effect, but this term is not much used, and the mesomeric and
electromeric effects tend to be subsumed in the term resonance effect of a substituent.;
Origin ID : M03844;
See also
The effect (on reaction rates, ionization equilibria, etc.) attributed to a substituent
due to overlap of its p- or π-orbitals with the p- or π-orbitals of the rest of the
molecular entity. delocalization is thereby introduced or extended, and electronic
charge may flow to or from the substituent. The effect is symbolized by M. Strictly
understood, the mesomeric effect operates in the ground electronic state of the molecule.
When the molecule undergoes electronic excitation or its energy is increased on the
way to the transition state of a chemical reaction, the mesomeric effect may be enhanced
by the electromeric effect, but this term is not much used, and the mesomeric and
electromeric effects tend to be subsumed in the term resonance effect of a substituent.
