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Preferred Label : telomerization;

IUPAC definition : The formation of an addition oligomer, having uniform end groups X' ... X'' , by a chain reaction in which a chain transfer limits the length of the polymer ('telomer') produced. An example is the polymerization of styrene in bromotrichloromethane solution (X' CCl sub 3 /sub , X'' Br), where Cl sub 3 /sub C· radicals are formed in the initiation step to produce Cl sub 3 /sub C[CH sub 2 /sub CHPh] sub i n /i /sub Br, with n greater than 1 and often less than i ca /i . 10:;

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The formation of an addition oligomer, having uniform end groups X' ... X'' , by a chain reaction in which a chain transfer limits the length of the polymer ('telomer') produced. An example is the polymerization of styrene in bromotrichloromethane solution (X' CCl sub 3 /sub , X'' Br), where Cl sub 3 /sub C· radicals are formed in the initiation step to produce Cl sub 3 /sub C[CH sub 2 /sub CHPh] sub i n /i /sub Br, with n greater than 1 and often less than i ca /i . 10:

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04/05/2025


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