Preferred Label : Esin and Markov coefficient;
IUPAC definition : The left-hand side of one of the various cross-differential relationships that can
be obtained from the Gibbs adsorption equation when only one chemical potential (µ)
is considered as variable, viz. \[(\frac{ E}{ μ })_{T,p,σ } - (\frac{ \mathit{γ
}}{ σ })_{T,p,μ }\] where E is the potential difference, T is the temperature, p
is the pressure, Γ is the surface excess and σ is the charge density.;
Origin ID : E02218;
See also
The left-hand side of one of the various cross-differential relationships that can
be obtained from the Gibbs adsorption equation when only one chemical potential (µ)
is considered as variable, viz. \[(\frac{ E}{ μ })_{T,p,σ } - (\frac{ \mathit{γ
}}{ σ })_{T,p,μ }\] where E is the potential difference, T is the temperature, p
is the pressure, Γ is the surface excess and σ is the charge density.
