" /> Esin and Markov coefficient - CISMeF





Preferred Label : Esin and Markov coefficient;

IUPAC definition : The left-hand side of one of the various cross-differential relationships that can be obtained from the Gibbs adsorption equation when only one chemical potential (µ) is considered as variable, viz. \[(\frac{ E}{ μ })_{T,p,σ } - (\frac{ \mathit{γ }}{ σ })_{T,p,μ }\] where E is the potential difference, T is the temperature, p is the pressure, Γ is the surface excess and σ is the charge density.;

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The left-hand side of one of the various cross-differential relationships that can be obtained from the Gibbs adsorption equation when only one chemical potential (µ) is considered as variable, viz. \[(\frac{ E}{ μ })_{T,p,σ } - (\frac{ \mathit{γ }}{ σ })_{T,p,μ }\] where E is the potential difference, T is the temperature, p is the pressure, Γ is the surface excess and σ is the charge density.

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29/07/2025


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