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Preferred Label : surface excess;

Detailed label : surface excess, nσ;

IUPAC definition : For an interface, the adsorption or surface excess of a given component is defined as the difference between the amount of component actually present in the system, and that which would be present (in a reference system) if the bulk concentration in the adjoining phases were maintained up to a chosen geometrical dividing surface (Gibbs dividing surface). For a solid/liquid interface in which no component of the liquid phase penetrates into the solid, the surface excess (or adsorption) of component i i /i is defined as: \[n_{i} {σ } n_{i}- V {{l}}\ c_{i} {{l}}\] where n i is the total amount of i i /i in the system, V l is the volume of an arbitrarily chosen amount of bulk liquid (in the framework of the so-called algebraic method) and cil is its bulk concentration in the liquid.;

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For an interface, the adsorption or surface excess of a given component is defined as the difference between the amount of component actually present in the system, and that which would be present (in a reference system) if the bulk concentration in the adjoining phases were maintained up to a chosen geometrical dividing surface (Gibbs dividing surface). For a solid/liquid interface in which no component of the liquid phase penetrates into the solid, the surface excess (or adsorption) of component i i /i is defined as: \[n_{i} {σ } n_{i}- V {{l}}\ c_{i} {{l}}\] where n i is the total amount of i i /i in the system, V l is the volume of an arbitrarily chosen amount of bulk liquid (in the framework of the so-called algebraic method) and cil is its bulk concentration in the liquid.

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29/07/2025


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