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Preferred Label : Z-value;

IUPAC definition : An index of the ionizing power of a solvent based on the frequency of the longest wavelength electronic absorption maximum of 1-ethyl-4-methoxycarbonylpyridinium iodide in the solvent. The i Z /i -value is defined by: \[Z \frac{2.859\,\times\,10 {4}}{\lambda}\] where Z is in kcal mol-1 and λ is in nm.;

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An index of the ionizing power of a solvent based on the frequency of the longest wavelength electronic absorption maximum of 1-ethyl-4-methoxycarbonylpyridinium iodide in the solvent. The i Z /i -value is defined by: \[Z \frac{2.859\,\times\,10 {4}}{\lambda}\] where Z is in kcal mol-1 and λ is in nm.

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20/05/2024


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