" /> π σ* transition - CISMeF





Preferred Label : π σ* transition;

IUPAC definition : An electronic transition described approximately as a promotion of an electron from a 'bonding' orbital π to an 'antibonding' orbital σ designated as σ*. Such transitions generally involve high transition energies and appear close to or mixed with Rydberg transitions.;

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An electronic transition described approximately as a promotion of an electron from a 'bonding' orbital π to an 'antibonding' orbital σ designated as σ*. Such transitions generally involve high transition energies and appear close to or mixed with Rydberg transitions.

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08/07/2025


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