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Preferred Label : photodeconjugation;

IUPAC definition : Photoinduced reaction of conjugated compounds (e.g., enones and carboxylic acid derivatives) leading to loss of conjugation.;

Scope note : this reaction has important synthetic applications for the synthesis of frameworks of numerous natural products, such asß,¿-unsaturated carboxylic acids from photoexcitation ofa,ß-unsaturated carboxylic acid derivatives, excluding the use of strong bases, as required for similar isomerizations performed in the ground state.;

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Photoinduced reaction of conjugated compounds (e.g., enones and carboxylic acid derivatives) leading to loss of conjugation.

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30/07/2025


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