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Preferred Label : primary isotope effect;

IUPAC definition : A kinetic isotope effect attributable to isotopic substitution of an atom to which a bond is made or broken in the rate-controlling step or in a pre-equilibrium step of a specified reaction. The corresponding isotope effect on the equilibrium constant of a reaction in which one or more bonds to isotopic atoms are broken, is called a 'primary equilibrium isotope effect'.;

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A kinetic isotope effect attributable to isotopic substitution of an atom to which a bond is made or broken in the rate-controlling step or in a pre-equilibrium step of a specified reaction. The corresponding isotope effect on the equilibrium constant of a reaction in which one or more bonds to isotopic atoms are broken, is called a 'primary equilibrium isotope effect'.

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30/07/2025


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