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Preferred Label : planar chirality;

IUPAC acronym : R;

IUPAC definition : Term used by some authorities to refer to stereoisomerism resulting from the arrangement of out-of-plane groups with respect to a plane (chirality plane ). It is exemplified by the atropisomerism of ( i E /i )-cyclooctene (chiral plane double bond and attached atoms) or monosubstituted paracyclophane (chiral plane substituted ring). The configuration of molecular entities possessing planar chirality is specified by the stereodescriptors R p and S p (or P and M).;

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Term used by some authorities to refer to stereoisomerism resulting from the arrangement of out-of-plane groups with respect to a plane (chirality plane ). It is exemplified by the atropisomerism of ( i E /i )-cyclooctene (chiral plane double bond and attached atoms) or monosubstituted paracyclophane (chiral plane substituted ring). The configuration of molecular entities possessing planar chirality is specified by the stereodescriptors R p and S p (or P and M).

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07/05/2025


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