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Preferred Label : oxidative addition;

IUPAC definition : The insertion of a metal complex into a covalent bond involving formally an overall two-electron loss on one metal or a one-electron loss on each of two metals, i.e. \[{L}_{n}{M} {m} {XY}\rightarrow {L}_{n}{M} {m 2}\left({X}\right)\left({Y}\right)\] or \[2{L}_{n}{M} {m} {XY}\rightarrow {L}_{n}{M} {m 1}\left({X}\right) {L}_{n}{M} {m 1}\left({Y}\right)\] In radical chemistry, the term is used to indicate a radical addition to a carbon–carbon double bond, under oxidative conditions. For example:;

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The insertion of a metal complex into a covalent bond involving formally an overall two-electron loss on one metal or a one-electron loss on each of two metals, i.e. \[{L}_{n}{M} {m} {XY}\rightarrow {L}_{n}{M} {m 2}\left({X}\right)\left({Y}\right)\] or \[2{L}_{n}{M} {m} {XY}\rightarrow {L}_{n}{M} {m 1}\left({X}\right) {L}_{n}{M} {m 1}\left({Y}\right)\] In radical chemistry, the term is used to indicate a radical addition to a carbon–carbon double bond, under oxidative conditions. For example:

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08/07/2025


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