" /> oxa-di-π-methane rearrangement - CISMeF





Preferred Label : oxa-di-π-methane rearrangement;

IUPAC definition : A photochemical reaction of a β,γ-unsaturated ketone to form a saturated α-cyclopropyl ketone. The rearrangement formally amounts to a 1,2-acyl shift and 'bond formation' between the former α and γ carbon atoms.;

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A photochemical reaction of a β,γ-unsaturated ketone to form a saturated α-cyclopropyl ketone. The rearrangement formally amounts to a 1,2-acyl shift and 'bond formation' between the former α and γ carbon atoms.

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28/07/2025


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