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Preferred Label : method of isotopic perturbation;

IUPAC definition : NMR shift difference measurement of the isotope effect on a fast (degenerate) equilibrium between two species which are equivalent except for isotopic substitution. This can be used to distinguish a rapidly equilibrating mixture with time-averaged symmetry from a single structure with higher symmetry.;

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NMR shift difference measurement of the isotope effect on a fast (degenerate) equilibrium between two species which are equivalent except for isotopic substitution. This can be used to distinguish a rapidly equilibrating mixture with time-averaged symmetry from a single structure with higher symmetry.

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06/05/2025


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