Preferred Label : medium effect;
IUPAC definition : The medium effect on ionic species B due to transfer from solvent S 1 to solvent S
2 (number) is defined by \[R\ T\ \ln γ _{{S}_{1}} {{S}_{2}}\left({B}\right) μ _{{B}}
{{o},{S}_{2}}- μ _{{B}} {{o},{S}_{1}}\] where R is the gas constant, T is the thermodynamic
temperature and µ B o , S i is the standard chemical potential of B in solvent S i
(where i 1 or 2), the reference states being the same in both solvents. γ S 1 S
2 B is not an exactly measurable quantity.;
Origin ID : M03815;
Automatic exact mappings (from CISMeF team)
- See also
The medium effect on ionic species B due to transfer from solvent S 1 to solvent S
2 (number) is defined by \[R\ T\ \ln γ _{{S}_{1}} {{S}_{2}}\left({B}\right) μ _{{B}}
{{o},{S}_{2}}- μ _{{B}} {{o},{S}_{1}}\] where R is the gas constant, T is the thermodynamic
temperature and µ B o , S i is the standard chemical potential of B in solvent S i
(where i 1 or 2), the reference states being the same in both solvents. γ S 1 S
2 B is not an exactly measurable quantity.
