" /> McLafferty rearrangement - CISMeF





Preferred Label : McLafferty rearrangement;

Detailed label : McLafferty rearrangement in mass spectrometry;

IUPAC definition : β-Cleavage with concomitant specific transfer of a γ-hydrogen atom in a six-membered transition state in mono-unsaturated systems, irrespective of whether the rearrangement is formulated by a radical or an ionic mechanism, and irrespective of the position of the charge.;

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β-Cleavage with concomitant specific transfer of a γ-hydrogen atom in a six-membered transition state in mono-unsaturated systems, irrespective of whether the rearrangement is formulated by a radical or an ionic mechanism, and irrespective of the position of the charge.

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29/07/2025


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