Preferred Label : McLafferty rearrangement;
Detailed label : McLafferty rearrangement in mass spectrometry;
IUPAC definition : β-Cleavage with concomitant specific transfer of a γ-hydrogen atom in a six-membered
transition state in mono-unsaturated systems, irrespective of whether the rearrangement
is formulated by a radical or an ionic mechanism, and irrespective of the position
of the charge.;
Origin ID : M03772;
See also
β-Cleavage with concomitant specific transfer of a γ-hydrogen atom in a six-membered
transition state in mono-unsaturated systems, irrespective of whether the rearrangement
is formulated by a radical or an ionic mechanism, and irrespective of the position
of the charge.
