" /> mass-transfer-controlled electrolyte rate constant - CISMeF





Preferred Label : mass-transfer-controlled electrolyte rate constant;

IUPAC definition : In controlled-potential coulometry and related techniques, the empirically evaluated constant of proportionality defined by the equation \[s_{{B}} - \frac{1}{c_{{B}}}\ \frac{\mathrm{d}c_{{B}}}{\mathrm{d}t}\] where cB is the bulk concentration of the substance B, and dc B dt is the rate of change of that concentration, resulting from the consumption of B by reduction or oxidation at the working electrode.;

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In controlled-potential coulometry and related techniques, the empirically evaluated constant of proportionality defined by the equation \[s_{{B}} - \frac{1}{c_{{B}}}\ \frac{\mathrm{d}c_{{B}}}{\mathrm{d}t}\] where cB is the bulk concentration of the substance B, and dc B dt is the rate of change of that concentration, resulting from the consumption of B by reduction or oxidation at the working electrode.

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23/05/2025


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