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Preferred Label : heterolytic bond-dissociation energy;

IUPAC definition : The energy required to break a given bond of some specific compound by heterolysis. For the dissociation of a neutral molecule AB in the gas phase into A sup class plus /sup and B sup class minus /sup the heterolytic bond-dissociation energy D(A sup class plus /sup B sup class minus /sup ) is the sum of the bond dissociation energy, i D /i (A–B), and the adiabatic ionization energy of the radical A· minus the electron affinity of the radical B·.;

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The energy required to break a given bond of some specific compound by heterolysis. For the dissociation of a neutral molecule AB in the gas phase into A sup class plus /sup and B sup class minus /sup the heterolytic bond-dissociation energy D(A sup class plus /sup B sup class minus /sup ) is the sum of the bond dissociation energy, i D /i (A–B), and the adiabatic ionization energy of the radical A· minus the electron affinity of the radical B·.

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29/07/2025


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