Preferred Label : gauche effect;
IUPAC definition : the destabilization of the gauche (synclinal) conformation in a two carbon unit bonded
vicinally to large, soft and polarizable elements such as sulfur and bromine.; the stabilization of the gauche (synclinal) conformation in a two carbon unit bonded
vicinally to electronegative elements e.g. 1,2-difluoroethane.;
Origin ID : G02595;
See also
the destabilization of the gauche (synclinal) conformation in a two carbon unit bonded
vicinally to large, soft and polarizable elements such as sulfur and bromine.
the stabilization of the gauche (synclinal) conformation in a two carbon unit bonded
vicinally to electronegative elements e.g. 1,2-difluoroethane.
