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Preferred Label : entrainment;

Detailed label : entrainment in photochemistry;

IUPAC definition : Term used in photostimulated radical nucleophilic substitution to designate the induction of the reaction of a less reactive (or non-reactive) nucleophile with a substrate by the addition of catalytic amounts of another nucleophile, more reactive at initiation. Often, the non-reactive nucleophile at initiation is, however, quite reactive at propagation.;

Scope note : term also used in photobiology in connection with the setting of the circadian clock by biological photosensors such as phytochromes and cryptochromes in plants and cryptochromes in mammals and insects.;

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Term used in photostimulated radical nucleophilic substitution to designate the induction of the reaction of a less reactive (or non-reactive) nucleophile with a substrate by the addition of catalytic amounts of another nucleophile, more reactive at initiation. Often, the non-reactive nucleophile at initiation is, however, quite reactive at propagation.

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08/05/2025


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