Preferred Label : enforced concerted mechanism;
IUPAC definition : Variation of reaction parameters in a series of reactions proceeding in non-concerted
steps may lead to a situation where the putative intermediate will possess a lifetime
shorter than a bond vibration, so that the steps become concerted. The transition
state structure will lie on the coordinate of the More O'Ferrall–Jencks diagram leading
to that of the putative intermediate.;
Origin ID : E02119;
See also
Variation of reaction parameters in a series of reactions proceeding in non-concerted
steps may lead to a situation where the putative intermediate will possess a lifetime
shorter than a bond vibration, so that the steps become concerted. The transition
state structure will lie on the coordinate of the More O'Ferrall–Jencks diagram leading
to that of the putative intermediate.
