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Preferred Label : endo, exo, syn, anti;

IUPAC definition : Descriptors of the relative orientation of groups attached to non-bridgehead atoms in a bicyclo[ i x.y.z /i ]alkane ( i x /i i y /i > i z /i > 0). If the group is orientated towards the highest numbered bridge ( i z /i bridge, e.g. C-7 in example below) it is given the description i exo /i ; if it is orientated away from the highest numbered bridge it is given the description i endo /i . If the group is attached to the highest numbered bridge and is orientated towards the lowest numbered bridge ( i x /i bridge, e.g. C-2 in example below) it is given the description i syn /i ; if the group is orientated away from the lowest numbered bridge it is given the description i em anti /em /i .;

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Descriptors of the relative orientation of groups attached to non-bridgehead atoms in a bicyclo[ i x.y.z /i ]alkane ( i x /i i y /i > i z /i > 0). If the group is orientated towards the highest numbered bridge ( i z /i bridge, e.g. C-7 in example below) it is given the description i exo /i ; if it is orientated away from the highest numbered bridge it is given the description i endo /i . If the group is attached to the highest numbered bridge and is orientated towards the lowest numbered bridge ( i x /i bridge, e.g. C-2 in example below) it is given the description i syn /i ; if the group is orientated away from the lowest numbered bridge it is given the description i em anti /em /i .

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05/05/2025


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