" /> encounter complex - CISMeF





Preferred Label : encounter complex;

IUPAC definition : A complex of molecular entities produced at an encounter-controlled rate, and which occurs as an intermediate in a reaction mechanism. When the complex is formed from two molecular entities it is called an 'encounter pair'. A distinction between encounter pairs and (larger) encounter complexes may be relevant in some cases, e.g. for mechanisms involving pre-association.;

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A complex of molecular entities produced at an encounter-controlled rate, and which occurs as an intermediate in a reaction mechanism. When the complex is formed from two molecular entities it is called an 'encounter pair'. A distinction between encounter pairs and (larger) encounter complexes may be relevant in some cases, e.g. for mechanisms involving pre-association.

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28/07/2025


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