" /> element effect - CISMeF





Preferred Label : element effect;

IUPAC definition : The ratio of the rate constants of two reactions that differ only in the identity of the element of the atom in the leaving group, e.g. kBr/kCl. As for isotope effects, a ratio of unity is regarded as a 'null effect'.;

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The ratio of the rate constants of two reactions that differ only in the identity of the element of the atom in the leaving group, e.g. kBr/kCl. As for isotope effects, a ratio of unity is regarded as a 'null effect'.

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05/05/2025


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