" /> eighteen-electron rule - CISMeF





Preferred Label : eighteen-electron rule;

IUPAC definition : An electron-counting rule to which an overwhelming majority of stable diamagnetic transition metal complexes adhere. The number of nonbonded electrons at the metal plus the number of electrons in the metal-ligand bonds should be 18. The 18 electron rule in transition metal chemistry is a full analogue of the 'Lewis octet rule'.;

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An electron-counting rule to which an overwhelming majority of stable diamagnetic transition metal complexes adhere. The number of nonbonded electrons at the metal plus the number of electrons in the metal-ligand bonds should be 18. The 18 electron rule in transition metal chemistry is a full analogue of the 'Lewis octet rule'.

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04/05/2025


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