" /> de Mayo reaction - CISMeF





Preferred Label : de Mayo reaction;

IUPAC definition : Photochemical process leading to the formation of cyclobutanols by cycloaddition of an alkene to a 1,3-dicarbonyl-enol. The enol originates in most cases from the tautomerization of a 1,3-dicarbonyl compound. The products of the de Mayo reaction are susceptible to undergo a retro-aldol ring opening resulting in the formation of 1,5-dicarbonyl compounds.;

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Photochemical process leading to the formation of cyclobutanols by cycloaddition of an alkene to a 1,3-dicarbonyl-enol. The enol originates in most cases from the tautomerization of a 1,3-dicarbonyl compound. The products of the de Mayo reaction are susceptible to undergo a retro-aldol ring opening resulting in the formation of 1,5-dicarbonyl compounds.

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29/07/2025


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