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Preferred Label : distribution isotherm;

Detailed label : distribution isotherm in chromatography;

IUPAC definition : The equilibrium relation between the concentration of a sample component in the stationary phase cS, and in the mobile phase cM, expressed as a function cS f.cM. In some versions of chromatography, a distribution isotherm can be seen as a partition isotherm, an adsorption isotherm, or a combination of these, depending on the mechanism of separation.;

Scope note : the relation can be influenced also by concentrations of other sample components. csand cm are usually expressed per unit volume of the phase; cs may also be expressed per mass of the dry solid phase or per unit surface area.;

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The equilibrium relation between the concentration of a sample component in the stationary phase cS, and in the mobile phase cM, expressed as a function cS f.cM. In some versions of chromatography, a distribution isotherm can be seen as a partition isotherm, an adsorption isotherm, or a combination of these, depending on the mechanism of separation.

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05/05/2025


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