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Preferred Label : degenerate chain branching;

IUPAC definition : Sometimes chain branching is brought about by an intermediate which has a long lifetime compared with an ordinary free radical. If this intermediate can break down in different ways, only one of which leads to branching, there may be a relatively slow increase in the number of radicals, and there is said to be degenerate chain branching.;

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Sometimes chain branching is brought about by an intermediate which has a long lifetime compared with an ordinary free radical. If this intermediate can break down in different ways, only one of which leads to branching, there may be a relatively slow increase in the number of radicals, and there is said to be degenerate chain branching.

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03/07/2025


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