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Preferred Label : complex mechanism;

IUPAC definition : This term is sometimes applied to an elementary reaction which proceeds via an intermediate species having a lifetime longer than a few rotational periods, in contrast to a direct reaction. However, in view of the danger of confusion with a reaction occurring in more than one step (a composite reaction ) this usage is not to be recommended; it is better to use the terms complex-mode mechanism or complex-mode reaction.;

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This term is sometimes applied to an elementary reaction which proceeds via an intermediate species having a lifetime longer than a few rotational periods, in contrast to a direct reaction. However, in view of the danger of confusion with a reaction occurring in more than one step (a composite reaction ) this usage is not to be recommended; it is better to use the terms complex-mode mechanism or complex-mode reaction.

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31/07/2025


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