Preferred Label : compensation effect;
IUPAC definition : In a considerable number of cases plots of TćS vs. ćH, for a series of reactions,
e.g. for a reaction in a range of different solvents, are straight lines of approximately
unit slope. Therefore, the terms ćH and TćS in the expression partially compensate,
and \[Δ {\ddagger}G Δ {\ddagger}H - T\ Δ {\ddagger}S\] often is a much simpler
function of solvent (or other) variation than ćH or TćS separately.;
Origin ID : C01197;
Automatic exact mappings (from CISMeF team)
- See also
In a considerable number of cases plots of TćS vs. ćH, for a series of reactions,
e.g. for a reaction in a range of different solvents, are straight lines of approximately
unit slope. Therefore, the terms ćH and TćS in the expression partially compensate,
and \[Δ {\ddagger}G Δ {\ddagger}H - T\ Δ {\ddagger}S\] often is a much simpler
function of solvent (or other) variation than ćH or TćS separately.
