Preferred Label : Bunnett–Olsen equations;
IUPAC definition : The equations for the relation between log 10 ( [SH ] [S] ) H 0 and log 10 [H
] H 0 for base S in aqueous mineral acid solution, where H0 is Hammett's acidity
function and log 10 [H ] H 0 represents the activity function log 10 ( γ S γ H
) γ SH for the nitroaniline reference bases to build H0. \[\log _{10}(\frac{{[SH}
{ }{]}}{{[S]}})- \log _{10}{[H} { }{]} (Φ - 1)\ (\log _{10}{[H} { }{]} H_{0}) pK_{{SH}
{ }}\] \[\log _{10}(\frac{{[SH} { }{]}}{[S]}) H_{0} Φ \ (\log _{10}{[H} { }{]} H_{0})
pK_{\mathrm{SH} { }}\];
Origin ID : B00758;
See also
The equations for the relation between log 10 ( [SH ] [S] ) H 0 and log 10 [H
] H 0 for base S in aqueous mineral acid solution, where H0 is Hammett's acidity
function and log 10 [H ] H 0 represents the activity function log 10 ( γ S γ H
) γ SH for the nitroaniline reference bases to build H0. \[\log _{10}(\frac{{[SH}
{ }{]}}{{[S]}})- \log _{10}{[H} { }{]} (Φ - 1)\ (\log _{10}{[H} { }{]} H_{0}) pK_{{SH}
{ }}\] \[\log _{10}(\frac{{[SH} { }{]}}{[S]}) H_{0} Φ \ (\log _{10}{[H} { }{]} H_{0})
pK_{\mathrm{SH} { }}\]
