Preferred Label : 'A' value;
IUPAC definition : The conformational preference of an equatorial compared to an axial substituent in
a monosubstituted cyclohexane. This steric substituent parameter equals ΔrG in kcal
mol-1 for the equatorial to axial equilibration on cyclohexane. The values are also
known as 'Winstein–Holness' A values.;
Origin ID : A00012;
Automatic exact mappings (from CISMeF team)
- See also
The conformational preference of an equatorial compared to an axial substituent in
a monosubstituted cyclohexane. This steric substituent parameter equals ΔrG in kcal
mol-1 for the equatorial to axial equilibration on cyclohexane. The values are also
known as 'Winstein–Holness' A values.
