Preferred Label : solvophobicity parameter;
Detailed label : solvophobicity parameter, Sp;
IUPAC definition : A solvent parameter defined by: \[Sp 1 - \frac{M}{M\left({hexadecane}\right)}\]
derived from the Gibbs energy of transfer (Δ t G ) of a series of solutes from water
to numerous aqueous-organic mixtures and to pure solvents: \[Δ _{{t}}G {\,\unicode{x26ac}}\left({to
solvent}\right) M\ R_{{T}} D\] where R T is a solute parameter, and M and D characterize
the solvent. The M values are used to define a solvent solvophobic effect so that
Sp values are scaled from unity (water) to zero (hexadecane).;
Origin ID : S05763;
See also
A solvent parameter defined by: \[Sp 1 - \frac{M}{M\left({hexadecane}\right)}\]
derived from the Gibbs energy of transfer (Δ t G ) of a series of solutes from water
to numerous aqueous-organic mixtures and to pure solvents: \[Δ _{{t}}G {\,\unicode{x26ac}}\left({to
solvent}\right) M\ R_{{T}} D\] where R T is a solute parameter, and M and D characterize
the solvent. The M values are used to define a solvent solvophobic effect so that
Sp values are scaled from unity (water) to zero (hexadecane).
