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Preferred Label : relative retardation;

Detailed label : relative retardation in planar chromatography, Rrel;

IUPAC definition : A term which is equivalent to relative retention used in column chromatography: the ratio of the R F value of a component to the R F value of a standard (reference) substance. Since the mobile phase front is common for the two components, the R F value can be expressed directly as the ratio of the distances travelled by the spot of the compound of interest (bi) and the reference substance (bst) respectively: \[R_{{rel}} \frac{R_{{F}\left(i\right)}}{R_{{F}\left({st}\right)}} \frac{b_{i}}{b_{{st}}}\] In former nomenclatures the symbol R s was used to express relative retardation in planar chromatography. Because of its identity with the symbol for peak resolution the symbol R rel is suggested for relative retardation in planar chromatography.;

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A term which is equivalent to relative retention used in column chromatography: the ratio of the R F value of a component to the R F value of a standard (reference) substance. Since the mobile phase front is common for the two components, the R F value can be expressed directly as the ratio of the distances travelled by the spot of the compound of interest (bi) and the reference substance (bst) respectively: \[R_{{rel}} \frac{R_{{F}\left(i\right)}}{R_{{F}\left({st}\right)}} \frac{b_{i}}{b_{{st}}}\] In former nomenclatures the symbol R s was used to express relative retardation in planar chromatography. Because of its identity with the symbol for peak resolution the symbol R rel is suggested for relative retardation in planar chromatography.

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07/05/2025


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