Preferred Label : heat capacity of activation;
Detailed label : heat capacity of activation, Δ‡Cpo;
IUPAC definition : A quantity related to the temperature coefficient of Δ‡H (enthalpy of activation)
and Δ‡S (entropy of activation) according to the equations: \[Δ {\ddagger}C_{p}
(\frac{ Δ {\ddagger }H}{ T})_{p} T\ (\frac{ Δ {\ddagger }S}{ T})_{p}\] If the
rate constant is expressible in the form \[\ln k \frac{a}{T} b c\ \ln T {d}T,\]
then: \[Δ {\ddagger}C_{p} (c - 1)\ R 2\ {d}(R\ T)\] SI unit: J mol-1 K-1.;
Origin ID : H02754;
See also
A quantity related to the temperature coefficient of Δ‡H (enthalpy of activation)
and Δ‡S (entropy of activation) according to the equations: \[Δ {\ddagger}C_{p}
(\frac{ Δ {\ddagger }H}{ T})_{p} T\ (\frac{ Δ {\ddagger }S}{ T})_{p}\] If the
rate constant is expressible in the form \[\ln k \frac{a}{T} b c\ \ln T {d}T,\]
then: \[Δ {\ddagger}C_{p} (c - 1)\ R 2\ {d}(R\ T)\] SI unit: J mol-1 K-1.
