" /> electrode current density - CISMeF





Preferred Label : electrode current density;

Detailed label : electrode current density, j;

IUPAC definition : If the charging current is negligible, in the case of a single electrode reaction, the electrode current density (c.d.) of the electric current flowing through the electrode is related to the flux density of a species strong B /strong by the equation: \[j n\ \nu _{{B}} {-1}\ F\ \left(N_{{B}}\right)_{e}\] where (NB)e is the normal component of the vector NB at the electrode-solution interface, n is the charge number of the electrode reaction and νB is the stoichiometric number of species strong B /strong . The ratio n/νB is to be taken as positive if the species strong B /strong is consumed in a cathodic reaction or produced in an anodic reaction. Otherwise it is to be taken as negative. With the convention that the normal distance vector points into the electrolytic solution, a cathodic current is then negative, an anodic current positive.;

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If the charging current is negligible, in the case of a single electrode reaction, the electrode current density (c.d.) of the electric current flowing through the electrode is related to the flux density of a species strong B /strong by the equation: \[j n\ \nu _{{B}} {-1}\ F\ \left(N_{{B}}\right)_{e}\] where (NB)e is the normal component of the vector NB at the electrode-solution interface, n is the charge number of the electrode reaction and νB is the stoichiometric number of species strong B /strong . The ratio n/νB is to be taken as positive if the species strong B /strong is consumed in a cathodic reaction or produced in an anodic reaction. Otherwise it is to be taken as negative. With the convention that the normal distance vector points into the electrolytic solution, a cathodic current is then negative, an anodic current positive.

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15/05/2024


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