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Preferred Label : cathodic transfer coefficient;

Detailed label : cathodic transfer coefficient, αc;

IUPAC definition : For a reaction with a single rate-determining step \[\frac{\alpha _{{c}}}{\nu } -\frac{R\ T}{n\ F}\ (\frac{ (\ln ( I_{{c}} ))}{ E})_{T,p,c_{i},...}\] where αc is the cathodic transfer coefficient (number), R is the gas constant, T is the thermodynamic temperature, and ν the stoichiometric number giving the number of identical activated complexes formed and destroyed in the completion of the overall reaction as formulated with the transfer of n electrons.;

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For a reaction with a single rate-determining step \[\frac{\alpha _{{c}}}{\nu } -\frac{R\ T}{n\ F}\ (\frac{ (\ln ( I_{{c}} ))}{ E})_{T,p,c_{i},...}\] where αc is the cathodic transfer coefficient (number), R is the gas constant, T is the thermodynamic temperature, and ν the stoichiometric number giving the number of identical activated complexes formed and destroyed in the completion of the overall reaction as formulated with the transfer of n electrons.

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29/07/2025


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